Tungsten Trioxide Chemical Properties
Solubility:insoluble in water;soluble in alkali;slightly soluble in acid
Crystal structure:Monoclinic system
Coordination geometry:Plane triangle
Hazard Symbols: None Listed
Risk Phrases: None Listed
Tungsten trioxide is stable in air, insoluble in water and inorganic acids except hydrofluoric acid, can slowly dissolve in ammonia and hot and concentrated sodium hydroxide solution. The reaction was heated to produce chlorine oxides with chlorine, but could not reacted with iodide and bromine.
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Ammonium paratungstate (APT) is an important intermediate compounds of tungsten hydrometallurgical process, appearance is white crystalline powder, insoluble in water, soluble in alcohol and ether.
Ammonium metatungstate(AMT) is an important intermediate compounds of tungsten hydrometallurgical process, appearance is white crystalline powder, solubility in water is the largest in the tungsten compounds which over 300g WO3/100ml H2O (in 25℃).
Sodium tungstate, a tungstate of sodium, is useful as a source of tungsten. It is prepared from tungsten ores used to manufacture tungsten by reducing it.
Tungstic acid refers to hydrated forms of tungsten trioxide, WO3. The simplest form, the monohydrate, is WO3H2O, the dihydrate WO3·2H2O is also known. The solid state structure of WO3· H2O consists of layers of octahedrally coordinated WO5(H2O) units where 4 vertices are shared.
Blue tungsten oxide refers to a class of dark blue compound containing tungsten (Ⅵ) and tungsten (V) mixed valence state. Blue tungsten oxide is the product of reductant and tungsten compounds. Composition of blue tungsten oxide is complex, among which there are also intermediate oxides like WO2 and W4.
Cesium tungsten bronze is inorganic nano material with good property in absorbing near-infrared with uniform grain size and dispersibility, it has strong absorbing function in near-infrared area with wave length 800~1200nm, also has high transmittance in visible light area with wave length 380~780nm.